Nitrogenous Synergists Induced Potentiometric Response to Metal Ions with Polymeric Liquid Membranes Containing Thenoyltrifluoroacetone as an Ionophore
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منابع مشابه
Nitrogenous synergists induced potentiometric response to metal ions with polymeric liquid membranes containing thenoyltrifluoroacetone as an ionophore.
The effects of nitrogenous synergists on the potentiometric responses to divalent transition metal ions were investigated concerning polymeric liquid membranes containing thenoyltrifluoroacetone (Htta) as an ionophore. The tested synergists were pyridine (py) and 4,4'-dioctyl-2,2'-bipyridyl (C8bpy). The potentiometric responses to metal ions, such as Cd2+, Co2+, Ni2+ and Zn2+, were induced by a...
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Tin(II)-ion-selective electrode consisting of dibenzo-18-crown-6 (DB18C6) as an ionophore inPVC matrix was developed. The influences of membrane composition, selectivity, response time,reversibility and temperature on the electrode performance were investigated. The electrodeshowed a near Nernstian response for Sn2+ ions over a concentration range from 1.0× 10-6 – 1.0× 10-2 M with a slope of 27...
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An equation that can describe the concentrations of ionic sites required for a Nernstian potentiometric response slope of neutral ionophore-incorporated ion-selective liquid membranes is presented. This equation is derived from a model based on electrical diffuse layers on both the membrane and the aqueous sides of the interface, in which the phase boundary potential is correlated to the surfac...
متن کاملpolymeric membrane sensor for potentiometric determination of tin(ii) ions
tin(ii)-ion-selective electrode consisting of dibenzo-18-crown-6 (db18c6) as an ionophore inpvc matrix was developed. the influences of membrane composition, selectivity, response time,reversibility and temperature on the electrode performance were investigated. the electrodeshowed a near nernstian response for sn2+ ions over a concentration range from 1.0× 10-6 – 1.0× 10-2 m with a slope of 27...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2006
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.22.219